钠离子电池负极材料原位透射电镜研究
陆佳宁,张智*,高义华,邹 进*- 摘要
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钠离子电池负极材料原位透射电镜研究
陆佳宁,张智*,高义华,邹 进*
(1.华中科技大学物理学院& 武汉光电国家研究中心, 湖北武汉430074;2.Materials Engineering & Centre for Microscopy and Microanalysis, The University of Queensland, St. Lucia, QLD 4072, Australia)
摘 要 近年来,由于地球上钠资源分布广泛和丰富,钠离子电池的研究引起了人们的极大兴趣。目前,钠离子电池仍面临着能量密度低、循环稳定性不理想等关键科学问题。钠离子电池存储性能的提高需要对其电极材料储钠微观机制的全面和精确的理解。尽管研究者们已经开展了大量的原位透射电子显微学研究来揭示钠离子电池负极材料的储钠特性和微观机制,但是相关的综述鲜见报道。鉴于此,本文综述了近年来原位透射电子显微镜在研究钠离子电池负极材料储钠过程中材料的形貌、微观结构和化学成分等的演化与微观机理的研究进展,阐明了钠离子电池负极材料的组成/结构与钠离子电池电化学性能之间的构效关联。本综述旨在为高效钠离子电池负极材料的高效选择和合理设计提供参考。
关键词 钠离子电池;负极材料;原位研究;透射电镜;
中图分类号:O646;TM911;TG115.21 文献标识码:A doi:10.3969/j.issn.1000-6281.2024.03.014
Study of anode materials for sodium-ion batteries byIn situ transmission electron microscopy
LU Jianing 1, ZHANG Zhi1*, GAO Yihua 1, ZOU Jin2*
(1. School of Physics & Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan 430074, China;2. Materials Engineering & Centre for Microscopy and Microanalysis, The University of Queensland, St. Lucia, QLD 4072, Australia)
Abstract Sodium-ion batteries (SIBs) have attracted increasing attentions in recent years due to the abundance and even distribution of Na resources on the earth.Currently, SIBs still face key scientific issues such as low energy density and unsatisfactory cycling stability.The improvement of the storage performance of SIBs requires a comprehensive and precise understanding of the microscopic mechanisms of sodium storage in their electrode materials.Although extensive in-situ transmission electron microscopy(TEM) investigations have been performed to provide mechanistic insights into the electrochemical performance of anode materialsof SIBs, a dedicated review for the in-situ TEM investigations on SIBs is missing in the literature. In this review, recent progress in the in-situ TEM investigations on dynamic transformation and the corresponding morphological, structural and chemical evolutions during the sodium storage process in the SIBs anode materials was summarized, elucidating the conformational correlation between the composition/structure of anode materials and electrochemical performance of sodium-ion batteries. This review aims to provide a reference for the efficient selection and rational design of anode materials for high-efficiency SIBs.
Keywords sodium-ion batteries;anode materials;in-situstudy;transmission electron microscopy
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[1] GROSJEAN C,MIRANDA P H. PERRIN M,et al. Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industry[J]. Renewable and Sustainable Energy Reviews, 2012, 16 (3):1735-1744.
[2] ARMAND M, TARASCON J M. Building better batteries[J]. Nature, 2008, 451(7179): 652-657.
[3] PALOMARES V, SERRAS P, VILLALUENGA I, et al. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems[J]. Energy & Environmental Science, 2012, 5(3): 5884-5901.
[4] LIU Q, YANG T, DU C, et al. In situ imaging the oxygen reduction reactions of solid state Na–O2 batteries with CuO nanowires as the air cathode[J]. Nano Letters, 2018, 18(6): 3723-3730.
[5] DELMAS C. Sodium and sodium‐ion batteries: 50 years of research[J]. Advanced Energy Materials, 2018, 8(17): 1703137.
[6] RODRIGUEZ J R, AGUIRRE S B, POL V G. Role of operando microscopy techniques on the advancement of sustainable sodium-ion battery anodes[J]. Journal of Power Sources, 2019, 437: 226851.
[7] LI Y, LU Y, CHEN L, et al. Failure analysis with a focus on thermal aspect towards developing safer Na-ion batteries[J]. Chinese Physics B, 2020, 29(4): 048201.
[8] CUI J, ZHENG H, HE K. In situ TEM study on conversion‐type electrodes for rechargeable ion batteries[J]. Advanced Materials, 2021, 33(6): 2000699.
[9] HUANG J Y, ZHONG L, WANG C M, et al. In situ observation of the electrochemical lithiation of a single SnO2 nanowire electrode[J]. Science, 2010, 330(6010): 1515-1520.
[10] XIE J, LI J, MAI W, et al. A decade of advanced rechargeable batteries development guided by in situ transmission electron microscopy[J]. Nano Energy, 2021, 83: 105780.
[11] YUAN Y, AMINE K, LU J, et al. Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy[J]. Nature Communications, 2017, 8(1): 15806.
[12] YOUSAF M, NASEER U, LI Y, et al. A mechanistic study of electrode materials for rechargeable batteries beyond lithium ions by in situ transmission electron microscopy[J]. Energy & Environmental Science, 2021, 14(5): 2670-2707.
[13] GU M, PARENT L R, MEHDI B L, et al. Demonstration of an electrochemical liquid cell for operando transmission electron microscopy observation of the lithiation/delithiation behavior of Si nanowire battery anodes[J]. Nano Letters, 2013, 13(12): 6106-6112.
[14] KARAKULINA O M, DEMORTIÈRE A, DACHRAOUI W, et al. In situ electron diffraction tomography using a liquid-electrochemical transmission electron microscopy cell for crystal structure determination of cathode materials for Li-ion batteries[J]. Nano Letters, 2018, 18(10): 6286-6291.
[15] WEN Y, HE K, ZHU Y, et al. Expanded graphite as superior anode for sodium-ion batteries[J]. Nature Communications, 2014, 5(1): 4033.
[16] WANG K, XU Y, LI Y, et al. Sodium storage in hard carbon with curved graphene platelets as the basic structural units[J]. Journal of Materials Chemistry A, 2019, 7(7): 3327-3335.
[17] JIAN Z, BOMMIER C, LUO L, et al. Insights on the mechanism of Na-ion storage in soft carbon anode[J]. Chemistry of Materials, 2017, 29(5): 2314-2320.
[18] LIU Y, FAN F, WANG J, et al.In situ transmission electron microscopy study of electrochemical sodiation and potassiation of carbon nanofibers[J]. Nano Letters, 2014, 14(6): 3445-3452.
[19] LI X, ZHAO L, LI P, et al. In-situ electron microscopy observation of electrochemical sodium plating and stripping dynamics on carbon nanofiber current collectors[J]. Nano Energy, 2017, 42: 122-128.
[20] ZHENG Y, ZHANG Z, LIU W, et al. Unveiling the Na-ions storage mechanism and sodiation-induced brittleness of multiwalled carbon nanotubes[J]. Journal of Power Sources, 2022, 532: 231357.
[21] YANG Y, TANG D M, ZHANG C, et al. “Protrusions” or “holes” in graphene: Which is the better choice for sodium ion storage?[J]. Energy & Environmental Science, 2017, 10(4): 979-986.
[22] WAN J, SHEN F, LUO W, et al. In situ transmission electron microscopy observation of sodiation–desodiation in a long cycle, high-capacity reduced graphene oxide sodium-ion battery anode[J]. Chemistry of Materials, 2016, 28(18): 6528-6535.
[23] DU F H, ZHANG L, TANG Y C, et al. Low‐temperature synthesis of amorphous silicon and its ball‐in‐ball hollow nanospheres as high‐performance anodes for sodium‐ion batteries[J]. Advanced Materials Interfaces, 2022, 9(9): 2102158.
[24] LU X, ADKINS E R, HE Y, et al. Germanium as a sodium ion battery material: In situ TEM reveals fast sodiation kinetics with high capacity[J]. Chemistry of Materials, 2016, 28(4): 1236-1242.
[25] HAN X, LIU Y, JIA Z, et al. Atomic-layer-deposition oxide nanoglue for sodium ion batteries[J]. Nano Letters, 2014, 14(1): 139-147.
[26] WANG J W, LIU X H, MAO S X, et al. Microstructural evolution of tin nanoparticles duringin situ sodium insertion and extraction[J]. Nano Letters, 2012, 12(11): 5897-5902.
[27] CAPONE I, ASPINALL J, DARNBROUGH E, et al. Electrochemo-mechanical properties of red phosphorus anodes in lithium, sodium, and potassium ion batteries[J]. Matter, 2020, 3(6): 2012-2028.
[28] LIU Y, LIU Q, JIAN C, et al. Red-phosphorus-impregnated carbon nanofibers for sodium-ion batteries and liquefaction of red phosphorus[J]. Nature Communications, 2020, 11(1): 2520.
[29] WU Y, XING F, XU R, et al. Spatially confining and chemically bonding amorphous red phosphorus in the nitrogen doped porous carbon tubes leading to superior sodium storage performance[J]. Journal of Materials Chemistry A, 2019, 7(14): 8581-8588.
[30] ZHU C, SHAO R, CHEN S, et al.In situ visualization of interfacial sodium transport and electrochemistry between few‐layer phosphorene[J]. Small Methods, 2019, 3(10): 1900061.
[31] KIM S, CUI J, DRAVID V P, et al. Orientation‐dependent intercalation channels for lithium and sodium in black phosphorus[J]. Advanced Materials, 2019, 31(46): 1904623.
[32] ZHUANG X, LI K, ZHANG T Y. Partial sodiation induced laminate structure and high cycling stability of black phosphorous for sodium-ion batteries[J]. Nanoscale, 2020, 12(38): 19609-19616.
[33] NIE A, CHENG Y, NING S, et al. Selective ionic transport pathways in phosphorene[J]. Nano Letters, 2016, 16(4): 2240-2247.
[34] CHEN T, ZHAO P, GUO X, et al. Two-fold anisotropy governs morphological evolution and stress generation in sodiated black phosphorus for sodium ion batteries[J]. Nano Letters, 2017, 17(4): 2299-2306.
[35] LI Z, TAN X, LI P, et al. Coupling in situ TEM and ex situ analysis to understand heterogeneous sodiation of antimony[J]. Nano Letters, 2015, 15(10): 6339-6348.
[36] ZHOU J, CHEN J, CHEN M, et al. Few‐layer bismuthene with anisotropic expansion for high‐areal‐capacity sodium‐ion batteries[J]. Advanced Materials, 2019, 31(12): 1807874.
[37] CHENG X, SHAO R, LI D, et al. A self‐healing volume variation three‐dimensional continuous bulk porous bismuth for ultrafast sodium storage[J]. Advanced Functional Materials, 2021, 31(22): 2011264.
[38] LIU H, CAO F, ZHENG H, et al.In situ observation of the sodiation process in CuO nanowires[J]. Chemical Communications, 2015, 51(52): 10443-10446.
[39] ZHANG L, WANG Y, XIE D, et al.In situ transmission electron microscopy study of the electrochemical sodiation process for a single CuO nanowire electrode[J]. RSC Advances, 2016, 6(14): 11441-11445.
[40] HU S, LIU H, ZHENG H, et al. Coating‐mediated nanomechanical behaviors of CuO electrodes in Li‐and Na‐ion batteries[J]. Advanced Materials Interfaces, 2020, 7(21): 2001161.
[41] LIU H, ZHENG H, LI L, et al. Surface‐coating‐mediated electrochemical performance in CuO nanowires during the sodiation–desodiation cycling[J]. Advanced Materials Interfaces, 2018, 5(4): 1701255.
[42] HE K, LIN F, ZHU Y, et al. Sodiation kinetics of metal oxide conversion electrodes: A comparative study with lithiation[J]. Nano Letters, 2015, 15(9): 5755-5763.
[43] ZHU C, XU F, MIN H, et al. Identifying the conversion mechanism of NiCo2O4 during sodiation–Desodiation cycling by in situ TEM[J]. Advanced Functional Materials, 2017, 27(17): 1606163.
[44] ZHU C, XU F, MIN H, et al. Identifying the conversion mechanism of NiCo2O4 during sodiation–Desodiation cycling by in situ TEM[J]. Advanced Functional Materials, 2017, 27(17): 1606163
[45] CHEN D, PENG L, YUAN Y, et al. Two-dimensional holey Co3O4 nanosheets for high-rate alkali-ion batteries: From rational synthesis to in situ probing[J]. Nano Letters, 2017, 17(6): 3907-3913.
[46] YUAN Y, MA L, HE K, et al. Dynamic study of (De) sodiation in alpha-MnO2 nanowires[J]. Nano Energy, 2016, 19: 382-390.
[47] ZHANG Z, QIAN J, LU W, et al. In situ TEM study of the sodiation/desodiation mechanism of MnO2 nanowire with gel-electrolytes[J]. Energy Storage Materials, 2018, 15: 91-97.
[48] CAI R, GUO S, WU Y, et al. Lattice-resolution visualization of anisotropic sodiation degrees and revelation of sodium storage mechanisms in todorokite-type MnO2 within-situ TEM[J]. Energy Storage Materials, 2021, 37: 345-353
[49] XIA W, XU F, ZHU C, et al. Probing microstructure and phase evolution of α-MoO3 nanobelts for sodium-ion batteries byin situ transmission electron microscopy[J]. Nano Energy, 2016, 27: 447-456.
[50] ZHENG Y, ZHANG Z, LIU W, et al. Investigations on the electrochemical and mechanical properties of Sb2O3 nanobelts by in situ transmission electron microscopy[J]. Small Methods, 2022, 6(3): 2101416.
[51] GU M, KUSHIMA A, SHAO Y, et al. Probing the failure mechanism of SnO2 nanowires for sodium-ion batteries[J]. Nano Letters, 2013, 13(11): 5203-5211.
[52] ASAYESH‐ARDAKANI H, YAO W, YUAN Y, et al.In situ TEM investigation of ZnO nanowires during sodiation and lithiation cycling[J]. Small Methods, 2017, 1(9): 1700202.
[53] XU F, LI Z, WU L, et al. In situ TEM probing of crystallization form-dependent sodiation behavior in ZnO nanowires for sodium-ion batteries[J]. Nano Energy, 2016, 30: 771-779.
[54] SU Q, DU G, ZHANG J, et al. In situ transmission electron microscopy observation of electrochemical sodiation of individual Co9S8-filled carbon nanotubes[J]. ACS Nano, 2014, 8(4): 3620-3627.
[55] BOEBINGER M G, YEH D, XU M, et al. Avoiding fracture in a conversion battery material through reaction with larger ions[J]. Joule, 2018, 2(9): 1783-1799.
[56] YAO L, XIA W, ZHANG H, et al. In situ visualization of sodium transport and conversion reactions of FeS2 nanotubes made by morphology engineering[J]. Nano Energy, 2019, 60: 424-431.
[57] HUANG S, LI Y, CHEN S, et al. Regulating the breathing of mesoporous Fe0. 95S1. 05 nanorods for fast and durable sodium storage[J]. Energy Storage Materials, 2020, 32: 151-158.
[58] BOEBINGER M G, XU M, MA X, et al. Distinct nanoscale reaction pathways in a sulfide material for sodium and lithium batteries[J]. Journal of Materials Chemistry A, 2017, 5(23): 11701-11709.
[59] XIA X, WANG Q, ZHU Q, et al. Improved Na-storage cycling of amorphous-carbon-sheathed Ni3S2 arrays and investigation by in situ TEM characterization[J]. Materials Today Energy, 2017, 5: 99-106.
[60] GAO P, WANG L, ZHANG Y, et al. Atomic-scale probing of the dynamics of sodium transport and intercalation-induced phase transformations in MoS2[J]. ACS Nano, 2015, 9(11): 11296-11301.
[61] ZHANG L, TANG Y, WANG Y, et al. In situ TEM observing structural transitions of MoS2 upon sodium insertion and extraction[J]. RSC Advances, 2016, 6(98): 96035-96038
[62] HUANG Q, WANG L, XU Z, et al.In-situ TEM investigation of MoS2 upon alkali metal intercalation[J]. Science China Chemistry, 2018, 61: 222-227
[63] YANG Z G, WU Z G, HUA W B, et al. Hydrangea‐like CuS with irreversible amorphization transition for high‐performance sodium‐Ion storage[J]. Advanced Science, 2020, 7(11): 1903279.
[64] WANG X, YAO Z, HWANG S, et al. In situ electron microscopy investigation of sodiation of titanium disulfide nanoflakes[J]. ACS Nano, 2019, 13(8): 9421-9430.
[65] HAN B, CHEN S, ZOU J, et al. Tracking sodium migration in TiS2 using in situ TEM[J]. Nanoscale, 2019, 11(15): 7474-7480.
[66] XU Y, WANG K, YAO Z, et al.In situ, atomic‐resolution observation of lithiation and sodiation of WS2 nanoflakes: implications for lithium‐ion and sodium‐ion batteries[J]. Small, 2021, 17(24): 2100637.
[67] LI Q, XU Y, YAO Z, et al. Revealing the effects of electrode crystallographic orientation on battery electrochemistry via the anisotropic lithiation and sodiation of ReS2[J]. ACS Nano, 2018, 12(8): 7875-7882.
[68] MA Z, YAO Z, CHENG Y, et al. All roads lead to Rome: Sodiation of different-stacked SnS2[J]. Nano Energy, 2020, 67: 104276.
[69] GAO P, ZHANG Y Y, WANG L, et al. In situ atomic-scale observation of reversible sodium ions migration in layered metal dichalcogenide SnS2 nanostructures[J]. Nano Energy, 2017, 32: 302-309.
[70] WANG X, YAO Z, HWANG S, et al. On the irreversible sodiation of tin disulfide[J]. Nano Energy, 2021, 79: 105458.
[71] CUI J, YAO S, LU Z, et al. Revealing pseudocapacitive mechanisms of metal dichalcogenide SnS2/graphene‐CNT aerogels for high‐energy Na hybrid capacitors[J]. Advanced Energy Materials, 2018, 8(10): 1702488.
[72] LI K, LIU X, QIN Y, et al. Sb2S3-Bi2S3 microrods with the combined action of carbon encapsulation and rGO confinement for improving high cycle stability in sodium/potassium storage[J]. Chemical Engineering Journal, 2021, 414: 128787.
[73] YAO S, CUI J, LU Z, et al. Unveiling the unique phase transformation behavior and sodiation kinetics of 1D van der Waals Sb2S3 anodes for sodium ion batteries[J]. Advanced Energy Materials, 2017, 7(8): 1602149.
[74] LI J, HAN S, ZHANG J, et al. Synthesis of three-dimensional free-standing WSe2/C hybrid nanofibers as anodes for high-capacity lithium/sodium ion batteries[J]. Journal of Materials Chemistry A, 2019, 7(34): 19898-19908.
[75] NIE A, GAN L, CHENG Y, et al. Ultrafast and highly reversible sodium storage in zinc‐antimony intermetallic nanomaterials[J]. Advanced Functional Materials, 2016, 26(4): 543-552.
[76] XIE H, TAN X, LUBER E J, et al. β-SnSb for sodium ion battery anodes: phase transformations responsible for enhanced cycling stability revealed by in situ TEM[J]. ACS Energy Letters, 2018, 3(7): 1670-1676.
[77] GUTIÉRREZ-KOLAR J S, BAGGETTO L, SANG X, et al. Interpreting electrochemical and chemical sodiation mechanisms and kinetics in tin antimony battery anodes using in situ transmission electron microscopy and computational methods[J]. ACS Applied Energy Materials, 2019, 2(5): 3578-3586
[78] WU Y, LUO W, GAO P, et al. Unveiling the microscopic origin of asymmetric phase transformations in (de) sodiated Sb2Se3 within situ transmission electron microscopy[J]. Nano Energy, 2020, 77: 105299.
[79] YANG Z, SUN J, NI Y, et al. Facile synthesis and in situ transmission electron microscopy investigation of a highly stable Sb2Te3/C nanocomposite for sodium-ion batteries[J]. Energy Storage Materials, 2017, 9: 214-220
[80] IHSAN-UL-HAQ M, HUANG H, WU J, et al. Thin solid electrolyte interface on chemically bonded Sb2Te3/CNT composite anodes for high performance sodium ion full cells[J]. Nano Energy, 2020, 71: 104613.
[81] SHEN H, MA Z, YANG B, et al. Sodium storage mechanism and electrochemical performance of layered GeP as anode for sodium ion batteries[J]. Journal of Power Sources, 2019, 433: 126682.
[82] SADDIQUE J, ZHANG X, WU T, et al. Enhanced silicon diphosphide-carbon composite anode for long-cycle, high-efficient sodium ion batteries[J]. ACS Applied Energy Materials, 2019, 2(3): 2223-2229.
[83] WANG Y, VON LIM Y, HUANG S, et al. Enhanced sodium storage kinetics by volume regulation and surface engineering via rationally designed hierarchical porous FeP@C/rGO[J]. Nanoscale, 2020, 12(7): 4341-4351.
[84] STEVENS D A, DAHN J R. Anin situ small‐angle X‐ray scattering study of sodium insertion into a nanoporous carbon anode material within an operating electrochemical cell[J]. Journal of The Electrochemical Society, 2000, 147(12): 4428.
[85] BOMMIER C, SURTA T W, DOLGOS M, et al. New mechanistic insights on Na-ion storage in nongraphitizable carbon[J]. Nano Letters, 2015, 15(9): 5888-5892.
[86] LUO W, JIAN Z, XING Z, et al. Electrochemically expandable soft carbon as anodes for Na-ion batteries[J]. ACS Central Science, 2015, 1(9): 516-522.
[87] 皇甫磊磊, 翟阿敏, 田鹤, 等. 碳纳米纤维储钠机制的原位透射电镜研究[J]. 电子显微学报, 2019, 38(6):593-599.
[88] 刘婷婷, 叶翰章, 李佳妮, 等. 镍-氮掺杂型碳纳米管材料的制备及其储钠性能研究[J]. 电子显微学报, 2021, 40(3):228-233.
[89] ZHANG Y, TAO L, XIE C, et al. Defect engineering on electrode materials for rechargeable batteries[J]. Advanced Materials, 2020, 32(7): 1905923.
[90] MORITO H, YAMADA T, IKEDA T, et al. Na–Si binary phase diagram and solution growth of silicon crystals[J]. Journal of Alloys and Compounds, 2009, 480(2): 723-726.
[91] 胡仁宗, 刘辛, 曾美琴, 等. 互不溶Sn-Al合金中自发生长Sn纳米线及其作为锂离子电池负极的电化学性能(英文)[J]. 电子显微学报, 2011, 30(6):494-504.
[92] LI J, WANG L, HE X. Phosphorus-based composite anode materials for secondary batteries[J]. Progress in Chemistry, 2016, 28(2/3): 193.
[93] SUN J, LEE H W, PASTA M, et al. A phosphorene–graphene hybrid material as a high-capacity anode for sodium-ion batteries[J]. Nature Nanotechnology, 2015, 10(11): 980-985.
[94] SU D, DOU S, WANG G. Bismuth: A new anode for the Na-ion battery[J]. Nano Energy, 2015, 12: 88-95.
[95] ALCÁNTARA R, JARABA M, LAVELA P, et al. NiCo2O4 spinel: First report on a transition metal oxide for the negative electrode of sodium-ion batteries[J]. Chemistry of Materials, 2002, 14(7): 2847-2848.
[96] WEN J W, ZHANG D W, ZANG Y, et al. Li and Na storage behavior of bowl-like hollow Co3O4 microspheres as an anode material for lithium-ion and sodium-ion batteries[J]. Electrochimica Acta, 2014, 132: 193-199.
[97] RAHMAN M M, SULTANA I, CHEN Z, et al. Ex situ electrochemical sodiation/desodiation observation of Co3O4 anchored carbon nanotubes: A high performance sodium-ion battery anode produced by pulsed plasma in a liquid[J]. Nanoscale, 2015, 7(30): 13088-13095.
[98] ZHOU Q, LIU L, HUANG Z, et al. Co3S4@ polyaniline nanotubes as high-performance anode materials for sodium ion batteries[J]. Journal of Materials Chemistry A, 2016, 4(15): 5505-5516.
[99] WU Y, ZHANG C, ZHAO H, et al. Recent advances in ferromagnetic metal sulfides and selenides as anodes for sodium-and potassium-ion batteries[J]. Journal of Materials Chemistry A, 2021, 9(15): 9506-9534.
[100] 杨方雯, 张凯, 吴哲敏, 等. 扫描透射电子显微镜原位揭示ZnO纳米片缺陷的动态演变机制[J]. 电子显微学报, 2023, 42(6):697-705
[101] 郑赫, 曹凡, 胡帅帅, 等. 低维材料原子尺度动态结构演变[J]. 电子显微学报, 2019, 38(5):436-444。
[102] 卢艳, 王立华, 邓青松, 等. 体心立方金属Mo纳米线拉伸塑性行为的原位透射电子显微镜观察[J]. 电子显微学报, 2014, 33(4):289-294.